Theremodynamics qn. paper Doubt

At 298K, the thermal expansion coefficient and the Isothermal compressibility of liquid water are \beta =2\times 10^{-4} \;\;\text{K}^{-1} and \kappa =4\times 10^{-6} \;\;\text{bar} respectively. Then, \left(\frac{\partial \text{U}}{\partial \text{V}}\right)_T for water at 300 K and P = 1.00 bar is :

a) 1.5 * 10^4 bar
b) 3 * 10^-4 bar
c) 6 * 10^-4 bar
d) 9 * 10^-4 bar

Q: In how many cases the entropy change is positive ,

SN1,SN2,SNi,E1,E2,E1cb ?

7 Answers

71
Vivek @ Born this Way ·

Q: In Solid PBr5, maximum number of d orbital(s) that take part in hybridization of P is X, then X is ?

Ans: 0

Q: No. of vibrational degrees of freedom of CO2 is ?

Q: Write tthe most appropriate structure of C3O2 ?

262
Aditya Bhutra ·

since solid PBr5 exists as [PBr4 ]+ Br-

hence it is sp3 hybrid.

262
Aditya Bhutra ·

in a linear molecule ,number of vibrational modes is 3N - 5, where N is the number of atoms in the molecule .

hence for CO2 , ans is 4

262
Aditya Bhutra ·

C3O2 is Carbon Suboxide

Structure -

O=C=C=C=O

71
Vivek @ Born this Way ·

For degree of freedom question, Do we have some more formulas like it in thermodynamics?. I didn't knew of any such formula.

262
Aditya Bhutra ·

even i didnt know this formula , just found it on google :)

71
Vivek @ Born this Way ·

hahahh! Try the rest two in the first post.. they are really good and easy looking questions.

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