Q1 there are many things missing which must be given in the question
it must be mentioned if the solutes are volatile or non volatile also density of water at 75°C must be given
let density of water given at this temp = d
also molar mass of solute is also necessary
for non volatile solutes:
vapour pressure of solution= p°x1
p°= original vp of solvent(water here)
x1= mf of solvent
now p° value for water at ntp/stp(25°C) is about 0.0263atm
using the formula:
ln(p2p1)=
Hv2.303R(T2-T1T2T1)
we can find vapour pressure of water at 75°C if we know the heat of vapourisation Hv of water
for calculating mf--> x1
molar mass of solute is required